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  1. Additively manufactured (AM) composites based on short carbon fibers possess strength and stiffness far less than their continuous fiber counterparts due to the fiber’s small aspect ratio and inadequate interfaces with the epoxy matrix. This investigation presents a route for preparing hybrid reinforcements for AM that comprise short carbon fibers and nickel-based metal-organic frameworks (Ni-MOFs). The porous MOFs furnish the fibers with tremendous surface area. Additionally, the MOFs growth process is non-destructive to the fibers and easily scalable. This investigation also demonstrates the viability of using Ni-based MOFs as a catalyst for growing multi-walled carbon nanotubes (MWCNTs) on carbon fibers. The changes to the fiber were examined via electron microscopy, X-ray scattering techniques, and Fourier-transform infrared spectroscopy (FTIR). The thermal stabilities were probed by thermogravimetric analysis (TGA). Tensile and dynamic mechanical analysis (DMA) tests were utilized to explore the effect of MOFs on the mechanical properties of 3D-printed composites. Composites with MOFs exhibited improvements in stiffness and strength by 30.2% and 19.0%, respectively. The MOFs enhanced the damping parameter by 700%. 
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  2. Abstract

    It is widely recognized that waves inhibit river mouth progradation and reduce the avulsion timescale of deltaic channels. Nevertheless, those effects may not apply to downdrift‐deflected channels. In this study, we developed a coupled model to explore the effects of wave climate asymmetry and alongshore sediment bypassing on shoreline‐channel morphodynamics. The shoreline position and channel trajectory are simulated using a “shoreline” module which drives the evolution of the river profile in a “channel” module by updating the position of river mouth boundary, whereas the channel module provides the sediment load to river mouth for the “shoreline” module. The numerical results show that regional alongshore sediment transport driven by an asymmetric wave climate can enhance the progradation of deltaic channels if sediment bypassing of the river mouth is limited, which is different from the common assumption that waves inhibit delta progradation. As such, waves can have a trade‐off effect on river mouth progradation that can further influence riverbed aggradation and channel avulsion. This trade‐off effect of waves is dictated by the net alongshore sediment transport, sediment bypassing at the river mouth, and wave diffusivity. Based on the numerical results, we further propose a dimensionless parameter that includes fluvial and alongshore sediment supply relative to wave diffusivity to predict the progradation and aggradation rates and avulsion timescale of deltaic channels. The improved understanding of progradation, aggradation, and avulsion timescale of deltaic channels has important implications for engineering and predicting deltaic wetland creation, particularly under changing water and sediment input to deltaic systems.

     
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